Solid Platinum Superoxo Hydroxo Complex
Solid Platinum Superoxo Hydroxo Complex. Pankratov D.A., Komozin P.N., Kiselev Yu.M. //Russian Journal of Inorganic Chemistry. 2000. V. 45. № 10. P. 1555-1559
Solid samples isolated from solutions of a platinum superoxo hydroxo complex are studied by EPR and X-ray powder diffraction techniques. The short-lived superoxo complex is found to form upon dissolution of the solid samples in concentrated acids. Magnetic resonance parameters of the platinum superoxo complexes in the solid state and in acidic solutions are determined. The structures of the inner coordination sphere of the found superoxo complexes are discussed.