Mono- and binuclear chloridecomplexes of bismuth (III) with 2-aminopyrimidine cations depending on specific synthetic route

Cover Mendeleev Communications March-April 2020 with stucture of complex Bi : 2-aminopyrimidine = 2 : 4 Mono- and binuclear chloridecomplexes of bismuth (III) with 2-aminopyrimidine cations depending on specific synthetic route. Trofimova T., Orlova M., Tafeenko V., Proshin A., Glazkova I., Pankratov D. //Mendeleev Communications. 2020. V.30. №2. P.202-204.

Complexes of BiIII with 2-aminopyrimidine cations with metal-to-ligand ratios of 1:3 or 2:4 (depending on reaction conditions) were synthesized and characterized by elemental analysis, 1H NMR spectroscopy, and single crystal X-ray crystallography. The possibility of conversion of the latter complex into the former one was demonstrated. The determined cytotoxicity depended on the structure of these complexes.

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