Mono- and binuclear chloridecomplexes of bismuth (III) with 2-aminopyrimidine cations depending on specific synthetic route
Mono- and binuclear chloridecomplexes of bismuth (III) with 2-aminopyrimidine cations depending on specific synthetic route. Trofimova T., Orlova M., Tafeenko V., Proshin A., Glazkova I., Pankratov D. //Mendeleev Communications. 2020. V.30. №2. P.202-204.
Complexes of BiIII with 2-aminopyrimidine cations with metal-to-ligand ratios of 1:3 or 2:4 (depending on reaction conditions) were synthesized and characterized by elemental analysis, 1H NMR spectroscopy, and single crystal X-ray crystallography. The possibility of conversion of the latter complex into the former one was demonstrated. The determined cytotoxicity depended on the structure of these complexes.